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Topic: Nylon Disolution  (Read 5623 times)

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Ski Dude

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Nylon Disolution
« on: July 15, 2005, 05:00:13 PM »
Looking for ways to disolve nylon fibers to separate and recycle nylon.
Disolved nylon in concentrated HCl solution, and then precipitated by diluting w/ water.

1) Why does this work?  Does it chemically react with or destroy the nylon?

2) Why does dilution precipitate the nylon?  Is it STILL nylon, or a chloride salt?

arnyk

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Re:Nylon Disolution
« Reply #1 on: July 15, 2005, 06:34:37 PM »
 [-NHCH2CH2CH2CH2CH2C-]n

There's Nylon 6/6.

It's a polymer made of hydrocarbons.  What kind of reaction do hydrocarbons undergo with HCl?  

H2C=CH2 + HCl --> H3C-CH2Cl

I may be forgetting a catalyst...but in your case the rx takes place in solution anyways.

Offline movies

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Re:Nylon Disolution
« Reply #2 on: July 15, 2005, 08:48:07 PM »
There are some carbonyls in there too, I'm pretty sure.  I think that nylon has amides bonding the two monomers together.

Offline HP

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Re:Nylon Disolution
« Reply #3 on: July 17, 2005, 12:57:23 PM »
Nylon(probably you mean polyamide6,6)may disolves in conc. H2SO4 or in formic acid. This is due to breaking intra and inter hydrogen bonds between amide bonds in the polymer chains. Ading H2O cause precipitation of the adid solutions due to reforming hydrogen bonds...
xpp

Ski Dude

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Re:Nylon Disolution
« Reply #4 on: July 20, 2005, 02:24:50 PM »
Is this really DISSOLVING  (in the true sense) or just a SUSPENSION of fine nylon particles?

Offline HP

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Re:Nylon Disolution
« Reply #5 on: July 21, 2005, 11:49:15 AM »
Yes it its absolutely real disolving. Polymers are not monomer agregates as some years before some people has tought :D
xpp

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