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Topic: Ionic Reactions  (Read 4268 times)

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Ionic Reactions
« on: July 22, 2005, 05:47:27 PM »
I have isolated copper from copper sulfate (CuSO4 . 5H2O ) - by the addition of aluminum to a solution of the above...


    It got me asking the question : Is this posible to do with aluminum ?

I.E. - make a solution of say aluminum chloride and react it with some other metal and get pure aluminum to form?

Well thanks for any help - even if you dont want to give me the answer please guide me in some obvious direction...

Thanks ...

Offline Borek

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Re:Ionic Reactions
« Reply #1 on: July 22, 2005, 06:09:12 PM »
Is this posible to do with aluminum ?

Google electronegativity series. Check if the water will not interfere.
« Last Edit: July 22, 2005, 06:13:24 PM by Borek »
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Offline lemonoman

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Re:Ionic Reactions
« Reply #2 on: July 23, 2005, 02:29:45 AM »
Agreed.  If you want to get realy technical, you can think of this addition as the creation of an electrochemical cell:

One reaction was Al(s) --> Al3+(aq) + 3 e-
And the other is Cu2+(aq) + 2 e- --> Cu(s)

And here's the deal.  If you write each as a reduction:
Al3+(aq) + 3 e- --> Al(s)
E = E°Al
Cu2+(aq) + 2 e- --> Cu(s)
E = E°Cu

Whenever you have two 'half reactions' like this, the one which has the lowest E° is more likely to occur as shown.  In your case, E°Cu would be lowest - hence the copper precipitate and the aluminum 'dissolves'.

All you need to do then is find a reaction like these, what occurs for a smaller number.  THAT will make the aluminum precipitate from the solution for the exact same reason as the copper did.

Good luck!

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