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Topic: phenyl esters + metal carbonate  (Read 2345 times)

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Offline bartek

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phenyl esters + metal carbonate
« on: May 04, 2010, 05:42:07 AM »
Will phenyl acetate (or generally - phenyl esters) be cloven to phenol and acetate salt, when refluxed with alkaline metal carbonate in anhydrous acetone or alcohol, or presence of water is essential?

Offline Doc Oc

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Re: phenyl esters + metal carbonate
« Reply #1 on: May 05, 2010, 01:51:46 PM »
I think in refluxing alcohol you'll just facilitate transesterification rather than hydrolysis of the ester.  Don't know about acetone, but if it's anhydrous I don't know if the carbonate salt would even dissolve.

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