Well, that's easy.
The concentration you have is for the entire molecule, CaCl2.
There's 1 mole of Ca per mole of CaCl2 (you can see that in the molecular formula), and there's 2 moles of Cl per mole of CaCl2 (again, the formula).
So that means the concentration of Ca is the same as the concentration of CaCl2, and the concentration of Cl is twice the conenctration of CaCl2.
Just look at the mole ratios compared to the entire molecule.