December 24, 2024, 12:17:53 PM
Forum Rules: Read This Before Posting


Topic: Interesting organic chemistry reagent  (Read 4271 times)

0 Members and 1 Guest are viewing this topic.

Offline LabRat01

  • Regular Member
  • ***
  • Posts: 24
  • Mole Snacks: +1/-0
Interesting organic chemistry reagent
« on: July 06, 2010, 11:35:10 AM »



Could anyone look at the TMS reagent I've attached and be able to tell me what happens when it reacts with water?

PS: I know the TMS will become TMS-OH, I'm more interested to know what happens to the N=C=N fragment...

Thank you



Offline OC pro

  • Chemist
  • Full Member
  • *
  • Posts: 396
  • Mole Snacks: +36/-15
  • Gender: Male
Re: Interesting organic chemistry reagent
« Reply #1 on: July 06, 2010, 01:21:45 PM »
It will form an urea derivative.

Offline LabRat01

  • Regular Member
  • ***
  • Posts: 24
  • Mole Snacks: +1/-0
Re: Interesting organic chemistry reagent
« Reply #2 on: July 06, 2010, 01:51:25 PM »
It will form an urea derivative.

Thanks

Offline ardbeg

  • Regular Member
  • ***
  • Posts: 82
  • Mole Snacks: +7/-3
Re: Interesting organic chemistry reagent
« Reply #3 on: July 06, 2010, 11:09:28 PM »
its a modified version of DCC, an amide coupling reagent.

Offline Agathiyar

  • Regular Member
  • ***
  • Posts: 19
  • Mole Snacks: +0/-0
Re: Interesting organic chemistry reagent
« Reply #4 on: July 10, 2010, 09:46:07 AM »
Is this commercially available? This is interesting because DCC is pain to use in large scale reactions, in this case the by-product urea might be water soulble and easy to remove from organics.

Offline LabRat01

  • Regular Member
  • ***
  • Posts: 24
  • Mole Snacks: +1/-0
Re: Interesting organic chemistry reagent
« Reply #5 on: July 14, 2010, 11:09:21 AM »
Is this commercially available? This is interesting because DCC is pain to use in large scale reactions, in this case the by-product urea might be water soulble and easy to remove from organics.

Yes, it's commercially available, I purschased 5x 5g bottles of it from Acros I think.

It's quite cheap too, if I remember correctly.

Offline AWK

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 7976
  • Mole Snacks: +555/-93
  • Gender: Male
Re: Interesting organic chemistry reagent
« Reply #6 on: July 15, 2010, 04:06:16 AM »
Bis(trimethylsilyl)carbodiimide shows also silylating properties
AWK

Sponsored Links