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Topic: arrenhius activation energy ratio?? pls help  (Read 2805 times)

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Offline abadir16

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arrenhius activation energy ratio?? pls help
« on: July 19, 2010, 12:22:55 PM »
In benzene solution, triethylamine, (C2H5)3N, reacts with bromoethane, C2H5Br, according to the following time-independent stoichiometric equation:

(C2H5)3N + C2H5Br = (C2H5)4N+Br−

If the ratio of the experimental rate constants at 333 K and 320 K (that is,
kR(333 K)/kR(320 K)) is equal to 2.0, use this information to estimate the Arrhenius activation energy for the reaction.       


choices are:

        136 kJ mol−1     
   21 kJ mol−1    
   75 kJ mol−1    
   47 kJ mol−1    
   93 kJ mol−1    

any help is appretiated.

Offline plankk

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Re: arrenhius activation energy ratio?? pls help
« Reply #1 on: July 19, 2010, 01:22:42 PM »
In the Arrhenius equation the preexponential factor is constant for reaction in every temperature. So you should educe the factor A from the Arrhenius equation and equate each other (in both temperatures) and from it find the value of activation energy.

Good luck!

Offline Dan

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Re: arrenhius activation energy ratio?? pls help
« Reply #2 on: July 20, 2010, 07:33:36 AM »
My research: Google Scholar and Researchgate

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