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Topic: Calculating Equilibrium Concentration of NO  (Read 2439 times)

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Offline phys

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Calculating Equilibrium Concentration of NO
« on: July 28, 2010, 07:30:40 PM »
QUESTION:
K=1.6 X 10-5 for the reaction

2 NOCl  ::equil:: 2 NO + Cl2

If 2.0 mol NO and 1.0 mol Cl2 are placed into a 1.0L flask, calculate the equilibrium concentration of NO.

Attempt:
Since the question being asked is for the reverse of this reaction, the value of K=62500 correct? Since Kf=1/Kr?
I set up an ICE table, but I can't seem to solve for x:

    2NO    Cl2    2NOCl
I    2.0     1.0    0.0
C   -2x     -x     +2x
E  2.0-2x  1.0-x  2x

K= [NOCl]2
    [NO]2[Cl2]

Have I got this all set up and right? If or if not, how do I solve for x? When I substitute the equations from the ICE table into the equilibrium constant equation and expand/simplify, I end up with an x3 that I can't use the Quadratic Formula to solve. ???

Offline Jorriss

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Re: Calculating Equilibrium Concentration of NO
« Reply #1 on: July 28, 2010, 08:05:19 PM »
A couple things. Can you use a calculator? If so, cubic roots are easy, if not, you'll need to do some approximations (there are methods for determining zeros but I doubt you are required to do those).


Secondly, your reaction doesn't correspond with your K expression. Either your K needs to be written as its reciprocal or your reaction is backwards.

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