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Topic: Why Nitrogen has strongest bond?  (Read 8426 times)

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Offline dijinj

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Why Nitrogen has strongest bond?
« on: September 02, 2010, 10:01:43 AM »
It came to me as a surprise that nitrogen has strongest bond. I learned that single bonds are strongest covalent bond. So why nitrogen having triple bonds has the strongest bond in diatomic molecules :)

Offline opti384

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Re: Why Nitrogen has strongest bond?
« Reply #1 on: September 02, 2010, 10:16:09 AM »
It's quite the opposite. Triple bonds are actually stronger than single bonds.

Offline Borek

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Re: Why Nitrogen has strongest bond?
« Reply #2 on: September 02, 2010, 02:19:20 PM »
Every bond in triple bond is weaker than a single bond, but there are three of them, and it is total strength that counts.
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Offline MrTeo

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Re: Why Nitrogen has strongest bond?
« Reply #3 on: September 02, 2010, 03:38:24 PM »
Every bond in triple bond is weaker than a single bond, but there are three of them, and it is total strength that counts.

Well, two bonds ($$ \pi /$$) are weaker but I think that the third ($$ \sigma /$$) has more or less the same energy of a single bond, am I wrong?
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Offline Jorriss

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Re: Why Nitrogen has strongest bond?
« Reply #4 on: September 02, 2010, 05:11:17 PM »
Every bond in triple bond is weaker than a single bond, but there are three of them, and it is total strength that counts.

Well, two bonds () are weaker but I think that the third () has more or less the same energy of a single bond, am I wrong?
Basically. For the purposes of this question, any C-x single bond has equal strength.

so, C-C, N-N, O-O are all 'relatively' equal.

But now, N2 has two more pi bonds on top of that single bond, while oxygen only has one pi bond enforcing it.

Offline dijinj

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Re: Why Nitrogen has strongest bond?
« Reply #5 on: September 04, 2010, 01:38:48 AM »
you mean the individual bonds in a triple bond is weaker than single bonds, or only total strength of all 3 bonds in a triple bond is higher, right? so the reaction N2 + 3 H2 > 2 NH3 is exothermic, right?
is oxidation of N2 is exothermic reaction with high threshold energy? I learned that Air ignites at very high temperature.
Can you suggest a good book that deals with calculations of energies of reaction( how to find out energy released or absorbed in reaction)

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