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Topic: Catalyst used in the Glovebox?  (Read 12589 times)

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Offline Enantiomer

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Catalyst used in the Glovebox?
« on: October 27, 2010, 09:40:03 PM »
Out of curiosity I've been looking for what catalyst it is that removes oxygen and water, I've heard that it is a 'Q5' catalyst but that doesn't ring a bell at all.

Anyone know?

Offline Doc Oc

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Re: Catalyst used in the Glovebox?
« Reply #1 on: October 28, 2010, 05:59:23 PM »
As far as I know it isn't a catalyst used to achieve this.  Oxygen is removed by repeatedly purging the box with nitrogen or argon.  I suppose dessicants can be added, maybe Drierite or something similar?  (It wasn't very humid at my school so we didn't worry as much about the moisture).

Offline MissPhosgene

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Re: Catalyst used in the Glovebox?
« Reply #2 on: October 28, 2010, 09:05:24 PM »
There is a Q5 catalyst, produced by BASF and DOW, but I couldn't find out what it is. It might be a copper based catalyst.

Here is a link to a site where it is mentioned:

http://www.ilpi.com/inorganic/glassware/glovebox.html

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Offline Enantiomer

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Re: Catalyst used in the Glovebox?
« Reply #3 on: October 29, 2010, 06:10:01 PM »
There is a Q5 catalyst, produced by BASF and DOW, but I couldn't find out what it is. It might be a copper based catalyst.

Here is a link to a site where it is mentioned:

http://www.ilpi.com/inorganic/glassware/glovebox.html
Yeah I saw this article too, I just figured that Q5 was a type or class of catalyst and wanted to know exactly the catalyst was

Offline macman104

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Re: Catalyst used in the Glovebox?
« Reply #4 on: November 02, 2010, 12:37:34 PM »
I believe Q5 is the actual catalyst that is used.  I found this paper, where they describe Q5 as 13% wt Cu(II)Oxide on Alumina.

http://dx.doi.org/10.1002/pola.20935

Offline 408

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Re: Catalyst used in the Glovebox?
« Reply #5 on: November 02, 2010, 01:25:19 PM »
I was always too lazy to do that in the gloveboxes I have used.  Instead I just left a lump of Na or K in the back in a beaker.

Offline wpenrose

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Re: Catalyst used in the Glovebox?
« Reply #6 on: November 03, 2010, 09:37:39 PM »
Those hand warmers sold in hunting and hardware shops contain iron powder and a few other things to promote rapid oxidation. They're handy for creating a moderately oxygen-free environment.

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