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Topic: Hydrobromic Acid Preperation  (Read 3228 times)

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Offline Eclipsonix

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Hydrobromic Acid Preperation
« on: December 13, 2010, 09:11:54 AM »
I'm having difficulty figuring out the best way to produce some HBr and later on some Elemental Bromine. I want to have the both basically

So far I'm finding preparations like (KBr + H2SO4), or (NaBr + H2SO4) to be common, but there's too many side reactions and byproducts.

I thought of why not use some of my hydrochloric acid 37% (is all I have) and buy some Sodium Bromide. My thinking is NaBr(ionic), HCl(polar covalent) would most likely react to form HBr and NaCl.

Somewhere on google a person recommended Peroxide(H2O2) as a oxidizing agent but I only have the weak store-bought 3% H2O2 H2O solution and have no clue if it would work, or exactly why it would help the reaction.

NaBr + HCl -> NaCl + HBr

without further recommendation I imagine adding HCl dropwise to a beaker of NaBr to form HBr which would then be seperated from the NaCl somehow. please suggest lol
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Offline Hybrid

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Re: Hydrobromic Acid Preperation
« Reply #1 on: December 13, 2010, 09:30:27 AM »
but HBr is stronger acid then HCl ??

Offline Eclipsonix

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Re: Hydrobromic Acid Preperation
« Reply #2 on: December 13, 2010, 09:44:19 AM »
Would that make a difference in not being able to work?
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Offline Eclipsonix

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Re: Hydrobromic Acid Preperation
« Reply #3 on: December 13, 2010, 10:31:34 AM »
http://www.youtube.com/watch?v=b9zB6_-vzSM&feature=related

I found this, anyone have good suggestions to it?

Let me get this right,

NaBr (s) + H2SO4 (aq) → HBr (aq) + NaHSO4 (aq)

and if I used H2O2 as an oxidizing agent I can avoid HBr and yield elemental Br?

NaBr (s) + H2SO4 (aq) + H2O2 (aq) → Br (aq) + NaHSO4 (aq)?  Please someone shine some light
« Last Edit: December 13, 2010, 10:48:00 AM by Eclipsonix »
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Offline vmelkon

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Re: Hydrobromic Acid Preperation
« Reply #4 on: January 01, 2011, 04:45:15 PM »
Someone had tried that and it produces very little Bromine.
Probably the easiest way is to use high conc H2SO4 and NaBr.
By electrolysis, a good way is to use ZnBr2 since its melting point is 300 C or in that range.

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