November 23, 2024, 11:47:30 PM
Forum Rules: Read This Before Posting


Topic: Math for integrated rate equations  (Read 2301 times)

0 Members and 1 Guest are viewing this topic.

Offline Boxxxed

  • Full Member
  • ****
  • Posts: 203
  • Mole Snacks: +1/-0
Math for integrated rate equations
« on: January 22, 2011, 02:25:29 PM »
I haven't done calculus in years so I'm confused with the following.

2H2O2 ----> 2H2O + O2

if

In[H2O2]t/[H2O2]0 = -kt = -0.106

Then

[H2O2]t/[H2O2]0 = 0.90 --->How do you arrive at this? How is the integral eliminated?

Offline rabolisk

  • Chemist
  • Full Member
  • *
  • Posts: 494
  • Mole Snacks: +45/-25
Re: Math for integrated rate equations
« Reply #1 on: January 22, 2011, 05:59:33 PM »
That's not an integral. It's a natural log. You just do the inverse of natural log (e-kt)
If your question is how does one derive the integrated rate law, then...

This is a separable differential equation.

You have the reaction 2H2O2  :rarrow: 2H2O + O2 which you know to be first-order with respect to H2O2.

This means that the rate of disappearance of H2O2 (also known as rate of reaction) is proportional to the concentration of H2O2. Mathematically, this can be represented as

$$ \frac{-d[A]}{dt} = k[A] /$$ where A is H2O2 and k is the rate constant.

Now I'm going to rearrange, then integrate both sides.

$$ \frac{-d[A]}{dt} = k[A] /$$
$$ \frac{d[A]}{[A]} = -kdt /$$
$$ \int \frac{d[A]}{[A]} = \int -kdt /$$
$$ \ln[A] = -kt + C /$$ where C is a constant (due to integration)
Left hand side always equals right hand side, and when t = 0, left hand side is
$$ \ln[A]_{0} = C /$$
So the overall equal is
$$ \ln[A]_{t} = -kt + \ln[A}_{0} /$$
$$ \ln\frac{[A]_{t}}{[A]_{0}} = -kt /$$

Sponsored Links