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Topic: TLC visualizing agent for Hydrazine derivatives  (Read 4947 times)

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Offline AMDS1987

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TLC visualizing agent for Hydrazine derivatives
« on: August 22, 2017, 12:58:54 AM »
I am synthesizing some hydrazine derivatives these days, when I check though UV (just checked) some spots are slightly visible but it is not conclusive. Can anyone suggest better method to visualize hydrazine (general speaking amine)? And the other trickiest point is hydrazine and other hydrazine derivatives I have both can be shown very closer polarity.

I would be so grateful if someone can suggest me a better method. I have already general TLC staining method they talk about amine and amino acids bit not specifically hydrazine.

Offline clarkstill

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Re: TLC visualizing agent for Hydrazine derivatives
« Reply #1 on: August 22, 2017, 06:01:36 AM »
Ninhydrin is the normal go-to for amines. I also like ceric ammonium molybdate as a general purpose stain.

Offline wildfyr

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Re: TLC visualizing agent for Hydrazine derivatives
« Reply #2 on: August 22, 2017, 04:17:19 PM »
I have yet to find something an iodine chamber doesn't stain. With that in mind, its totally nonselective.

Offline kriggy

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Re: TLC visualizing agent for Hydrazine derivatives
« Reply #3 on: August 23, 2017, 12:15:50 PM »
I suppose some kind of solution of dinitrofluorobenzene could work. Friend of mine made dinitrophenyl hydrazine and its quite orange

Offline AMDS1987

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Re: TLC visualizing agent for Hydrazine derivatives
« Reply #4 on: August 25, 2017, 02:19:19 AM »
Thank you all for your kind reply. I will try them

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