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Topic: Increasing Oxidation Levels  (Read 6357 times)

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Offline w451208

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Increasing Oxidation Levels
« on: January 27, 2011, 12:50:24 AM »




Could someone explain why these answers are the way they are? Especially number 11. What is the best way to determine the answer without wasting to much time.

Offline AC Prabakar

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Re: Increasing Oxidation Levels
« Reply #1 on: January 28, 2011, 06:22:02 AM »
Just count the number of (i)hetero atom attached to the carbon(consider each bond as one count-for ex. double bond  gives two count)(ii) number of the bonds of the carbon (consider each bond as one count-for ex. double bond  gives two count).
Sum of these two will give u the oxidation level.
Arranging this number in ascending order will give u the answer.
U can check it out for the above example also...

I hope u r well aware of oxidation state and level..

Offline cth

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Re: Increasing Oxidation Levels
« Reply #2 on: January 28, 2011, 09:25:42 AM »
For question 11, I am surprised with answer A.  ???
I found the oxidation numbers to be:

picture      I      II     III
ox. nb.     +1    +2     0

So I think it is the answer D instead.

http://en.wikipedia.org/wiki/Oxidation_state



Just count the number of (i)hetero atom attached to the carbon(consider each bond as one count-for ex. double bond  gives two count)(ii) number of the bonds of the carbon (consider each bond as one count-for ex. double bond  gives two count).
Sum of these two will give u the oxidation level.
Sorry but I am not sure I understand what you meant: (ii) number of the bonds of the carbon (consider each bond as one count-for ex. double bond  gives two count)
Taken like that, a carbon atom always has four bonds (except for a few special cases such as carbanions,...). That way of calculating oxidation numbers looks erroneous for me.

Offline AC Prabakar

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Re: Increasing Oxidation Levels
« Reply #3 on: January 29, 2011, 04:34:12 AM »
Ohh!!!
Pls check the difference between "oxidation state" and "Oxidation level".
I am talking about oxidation level not about oxidation state.
The question no 11 also about oxidation level!!!!

Of course Oxidation number of all the carbon in question no 11 is "+4" i.e. same, but not oxidation levels are same.

Pls follow the following link for further details on oxidation levels:

http://www.chemicalforums.com/index.php?topic=24299.0

If u r having "Organic chemistry" by Clayden and warren-book refer chapter-2 p.No-35-37

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