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Topic: Determining solubility from titration data  (Read 5016 times)

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Offline howsockgothappy

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Determining solubility from titration data
« on: March 22, 2011, 09:32:57 AM »
Hi, so I'm trying to do the calculations to go with our lab and am experiencing some confusion. It asks to determine the solubility of Ca(OH)2 using your titration data... Seems easy enough, I calculated the H+ moles from the amount of HCl used, set that equal to moles OH- since the titration should have been at the quivalence point, calculated concentration of OH- and then used that to calculate concentration of CA2+. I was pretty certain that using these I should be able to get the right answer for Ksp, and I did get sort of in the general ballpark.

My confusion comes at the end, where it asks for total concentration of OH- vs. the concentration of OH- provided by Ca(OH)2... I don't see how that fits into the calculations, or even how I can do that. It's Ca(OH)2 and HCl, so shouldn't the calcium hydroxide be the ONLY source of OH-?

Offline AWK

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Re: Determining solubility from titration data
« Reply #1 on: March 22, 2011, 09:50:37 AM »
For Ca(OH)2 you can safely neglect OH- ions from water autoprotolysis.
AWK

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