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Topic: Nitrosobenzene  (Read 2404 times)

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Offline SirRoderick

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Nitrosobenzene
« on: May 29, 2011, 01:50:56 PM »
So this is linked to my other, broader question but since I don't have any replies I figure I'd ask this seperately.

Nitrosobenzene, so Ph-N=O. How would the reaction mechanics work for an addition reaction to a carbon chain with a double bond? It should end up binding the N to the carbon chain and splitting off the O (presumably as water).
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Offline bolo

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Re: Nitrosobenzene
« Reply #1 on: May 30, 2011, 05:22:41 PM »
What kind of double bond do you mean? Towards an ordinary double bond it might not be as reactive as e.g. NOCl.
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Offline BluePill

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Re: Nitrosobenzene
« Reply #2 on: May 31, 2011, 12:24:04 AM »
This looks like a Hoffman rearrangement/Curtius. Hmm..
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