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Topic: Calculating heat of combustion?  (Read 3041 times)

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Offline Amina

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Calculating heat of combustion?
« on: June 05, 2011, 02:03:03 AM »
I've looked around and I'm finding it hard to grasp Hess' Law. I need to find the heat of combustion for Methanol and use delta H = -239.2
I am also using this equation:
2CH3OH + 3O2 --> 2CO2 + 4H2O

If anyone can help and take me through it step by step?
Thanks.

Offline Vidya

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Re: Calculating heat of combustion?
« Reply #1 on: June 05, 2011, 02:43:15 AM »
write equations for the heats of formations of CH3OH ,CO2 and H2O

Enthalpies of formations of these compounds can be taken from the reference tables .
Combine the equations to get the desired equation
Try it 

Offline Amina

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Re: Calculating heat of combustion?
« Reply #2 on: June 05, 2011, 02:52:11 AM »
I've tried writing the equations, but I don't think I've done them right:

2CH3OH --> 2C + 2H2 + 02 = H +478.4
2C + 2O2 --> 2CO2 = H -787
4H2 + 2O2 --> 4H2O = H - 967.2

They just seem wrong when I go to cross them out.

Offline Amina

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Re: Calculating heat of combustion?
« Reply #3 on: June 05, 2011, 09:16:20 AM »
I've tried writing the equations, but I don't think I've done them right:

2CH3OH --> 2C + 2H2 + 02 = H +478.4
2C + 2O2 --> 2CO2 = H -787
4H2 + 2O2 --> 4H2O = H - 967.2

They just seem wrong when I go to cross them out.

I see what I did wrong there :3 Never mind, I've answered it. And sorry, I don't know how to edit the post  :-[

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