June 22, 2024, 07:00:51 AM
Forum Rules: Read This Before Posting


« previous next »
Pages: [1]   Go Down

Topic: Major product of addition to alkyne?  (Read 3055 times)

0 Members and 1 Guest are viewing this topic.

Offline bmthog

  • Regular Member
  • ***
  • Posts: 23
  • Mole Snacks: +0/-0
Major product of addition to alkyne?
« on: October 19, 2011, 11:34:16 PM »
Please tell me what is the major product when 2-pentyne react with HgSO4/ dilute H2SO4?

How can we predict the major product from unsymmetric alkyne, does they follow Markov orientation?

Thanks in advance :)
Logged

Offline Dan

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 4716
  • Mole Snacks: +469/-72
  • Gender: Male
  • Organic Chemist
    • My research
Re: Major product of addition to alkyne?
« Reply #1 on: October 20, 2011, 03:33:51 AM »
Look up "oxymercuration" in any organic chemistry textbook.

A google for oxymercuration of alkynes will also help you.
Logged
My research: Google Scholar and Researchgate

Offline bmthog

  • Regular Member
  • ***
  • Posts: 23
  • Mole Snacks: +0/-0
Re: Major product of addition to alkyne?
« Reply #2 on: October 20, 2011, 04:58:34 AM »
@DAN: I did read "oxymercuration" mechanism, but can u confirm what is the major product, if follow Markov, it will be CH3-CH2-C(=O)-CH2-CH3 but my teacher said CH3-C(=O)-CH2CH2CH3 ???? I don't know why?
Logged

Offline Honclbrif

  • Chemist
  • Full Member
  • *
  • Posts: 659
  • Mole Snacks: +58/-10
  • Gender: Male
Re: Major product of addition to alkyne?
« Reply #3 on: October 20, 2011, 07:29:11 AM »
I don't think either would be favored and you'd get a roughly 1:1 mixture of the two ketones.
Logged
Individual results may vary
Pages: [1]   Go Up
« previous next »
Sponsored Links