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Topic: Extraction of acids and bases - calculation problem  (Read 5107 times)

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gingi

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Extraction of acids and bases - calculation problem
« on: October 11, 2005, 09:45:13 PM »
Hi guys.
I'm having some problems solving this problems. Help would be appreciated !

The distribution coefficient, k = (conc. i ligroin/conc/ in water) between ligroin and water for solute A is 7.5. What weight of A would be removed from a solution og 10 g of A in 100 mL of water by a single extraction with 100 mL of ligroin ?
What weight of A would br removed by four successive extractions with 25 mL portions of ligroin ?
How much ligroin would be required to remove 98.5% of A in a single extraction ?

I simply don't have any idea how to solve it. thanks again !
G

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Re:Extraction of acids and bases - calculation problem
« Reply #1 on: October 12, 2005, 08:34:11 AM »
This type of calculation is typically covered in an Analytical Chemistry course in the book chapter "Analytical Separations, separation by extraction".  There is a page or two algebra workup in the book that I have (Ch 24, Analytical Chemistry:  An Introduction, 5th ed, Skoog, Holler, West) followed by an example.  

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