I am not sure what p=m+b is.
The slope of a line generally refers to data plotted on a graph. The slope is the change in the y value over the change in the x value.
m = y2-y1/x2-x1
The equation for a straight line graph is y = mx+c (m = slope, c = intercept)
You basically have two data points in this question:
(x, y)
(pressure, temperature)
(1099, 22.3) and (1033, 29.0)
I am not sure why the pressure would go down when the sample was heated though?