You're question isn't very specific -- you use words like "very cold" without a reference point, so it's hard to give you a useful answer. Let me take a wild guess -- you're aware of ammonium nitrate dissolution in water being cold, and want something ... more. Looking at this favorite science webpage of mine, we see a list: http://antoine.frostburg.edu/chem/senese/101/thermo/faq/exothermic-endothermic-examples.shtml Right at the top is the endothermic "reaction" produced by melting ice. The change of state is certainly endothermic, fairly inexpensive, and pretty easy to deliver. Do you need something colder, or longer lasting? You can try other changes of state, like dry ice, or others.