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Topic: electronegativity of O in lewis structure of NO2  (Read 8070 times)

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de5truction

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electronegativity of O in lewis structure of NO2
« on: November 15, 2005, 12:23:57 AM »
my high school teacher stressed in a post-exam lecture that the bond between N and O can hardly be a dative because both are almost equally electronegative, so both are not willing to donate a pair of electron to the other.  is this the case?

Offline Donaldson Tan

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Re:electronegativity of O in lewis structure of NO2
« Reply #1 on: November 16, 2005, 11:10:33 PM »
oxygen is more electronegative than nitrogen. On the pauling scale, nitrogen is measured as 3.04 whereas oxygen is measured as 3.44. The difference of 0.4 represents about 20% of that oxygen. I would not consider that as negligible difference.

The only reason why there is no dative bond between N and O is that the octet rule does not allow it to happen.
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