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Topic: POCl3 reactivity  (Read 8575 times)

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bharathi

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POCl3 reactivity
« on: November 09, 2005, 02:34:01 AM »
Does POCl3 react with hydrogen peroxide?What could be the  possible products of this interaction?

Regards,
CHB
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Offline movies

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Re:POCl3 reactivity
« Reply #1 on: November 09, 2005, 02:39:57 AM »
POCl3 is a pretty wicked electrophile.  It will reaction with anything moderately nucleophilic.
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laotree

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Re:POCl3 reactivity
« Reply #2 on: November 13, 2005, 06:42:33 AM »
I have seen so many questions about POCl3 in this forum. Movies should give a general lecture about it.
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Arsenic

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Re:POCl3 reactivity
« Reply #3 on: November 13, 2005, 08:39:34 PM »
I have not seen anything on the direct reaction of hydrogen peroxide with POCl3 but considering the fact that H2O2 has some H2O impurity a reaction between H2O and POCl3 can be assumed.
« Last Edit: November 13, 2005, 08:40:56 PM by Arsenic »
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Offline Donaldson Tan

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Re:POCl3 reactivity
« Reply #4 on: November 30, 2005, 11:12:24 AM »
I think Arsenic's reaction might cause more H2O2 to break down, because not only water is consumed, but also this reaction is exothermic.
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