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Topic: Structural Formula and central atoms of CSiSe2H2  (Read 2933 times)

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Offline issacweirdo

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Structural Formula and central atoms of CSiSe2H2
« on: May 07, 2012, 11:52:33 PM »
Here's the Yahoo! answers topic that I have posted already. I think I got the right structural formula, but the C part is tripping me up. I also think the central atoms are Si and Se, but I'm not quite sure. I would like some confirmation and some explanation as to why C is stable (if it is) in this configuration!
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Offline AWK

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Re: Structural Formula and central atoms of CSiSe2H2
« Reply #1 on: May 08, 2012, 01:58:40 AM »
Why not H2C=Si=Se or H2Si=C=Se?
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Offline Dan

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Re: Structural Formula and central atoms of CSiSe2H2
« Reply #2 on: May 08, 2012, 11:40:59 AM »
Does a compound with that molecular formula exist?
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Offline sjb

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Re: Structural Formula and central atoms of CSiSe2H2
« Reply #3 on: May 08, 2012, 12:01:47 PM »
Quote from: Dan on May 08, 2012, 11:40:59 AM
Does a compound with that molecular formula exist?

Looks a tad unstable to me, the only formula I can think of is an extended sort of ketene structure; but looks very unstable to polymerisation or hydrolysis. Not sure if the carbon or the silicon should be at the end (a bit like AWK's, but aren't there 2 atoms of Se?).
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Offline cheese (MSW)

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Re: Structural Formula and central atoms of CSiSe2H2
« Reply #4 on: May 08, 2012, 12:40:56 PM »
The molecule is not listed on CAS so I am not sure why we are spending time on this beastie.
HSe-C≡Si-SeH looks reasonable but C≡Si bonds are as far as I'm aware unknown.  But I haven't been
following the field of SiSi multiple bonds for some time.
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Offline AWK

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Re: Structural Formula and central atoms of CSiSe2H2
« Reply #5 on: May 09, 2012, 02:00:51 AM »
I did not notice the second Se atom looking at Yahoo link.
Se=C=SiH(SeH) does not contain Si-C triple bond.
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