Shelf life depends on How often you use it and type of storage bottle. For 100 mL 1 ppm lead in 1-5% HNO3/water stored in PE or Glass bottle with PE or PTFE lid, I would expect shelf life to be about 3-6 months. You may want to keep old standards and re-analyse them from time to time. then you will be able to establish shelf life acceptable for your test.