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Topic: Calculate molality (Read 2812 times)
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professordad
Regular Member
Posts: 11
Mole Snacks: +1/-0
Calculate molality
«
on:
August 22, 2012, 10:46:08 AM »
A solution is made containing 7.5 g CH
3
OH in 245 g H
2
O. Calculate the molality of CH
3
OH.
Ok so what I did was: since molality is mol solute / kg solvent. We know that mol solute is 7.5 g CH
3
OH ยท (1 mol CH
3
OH) / (32.0419 g CH
3
OH) or 0.23 mol CH
3
OH.
Then for the kg solvent there's 245 g H
2
O which is basically 0.245 kg H
2
O.
So dividing thru we have m = 0.94.
But the right answer is m = 0.271...
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Hunter2
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Posts: 2298
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Re: Calculate molality
«
Reply #1 on:
August 22, 2012, 11:21:17 AM »
I get 0.96 mol/kg
«
Last Edit: August 22, 2012, 11:34:20 AM by Hunter2
»
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Borek
Mr. pH
Administrator
Deity Member
Posts: 27863
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I am known to be occasionally wrong.
Re: Calculate molality
«
Reply #2 on:
August 22, 2012, 11:31:25 AM »
Closer to 0.96 (0.9554) - you shouldn't round down number of moles so early.
But the "correct" answer is definitely incorrect.
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ChemBuddy
chemical calculators - stoichiometry, pH, concentration, buffer preparation,
titrations.info
professordad
Regular Member
Posts: 11
Mole Snacks: +1/-0
Re: Calculate molality
«
Reply #3 on:
August 23, 2012, 11:02:44 AM »
Ok thanks for your inputs!
@Borek: I round down early because my book taught me for significant digits calculations -- should I not do so in the future? Thanks.
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Borek
Mr. pH
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Deity Member
Posts: 27863
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I am known to be occasionally wrong.
Re: Calculate molality
«
Reply #4 on:
August 23, 2012, 12:22:51 PM »
You should do the calculations using full precision, and round down only the final result. That is, if you REPORT intermediate result, you should round it down as well, but you should not use rounded value for calculations.
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ChemBuddy
chemical calculators - stoichiometry, pH, concentration, buffer preparation,
titrations.info
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Calculate molality