Possibly the teacher is considering that any water present is in the form of waters of hydration? And that heating the popcorn is separating them from the starch?
In that case, using your definition of the starch, you might be looking at something like:
C
6H
12O
6·xH
2O
C
6H
12O
6 + xH
2O(g)
(Just be aware that starch is structurally more complicated than the formula you have written.)
This is a guess on my part - I can't think of any other line of reasoning that would invoke an empirical formula.