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Topic: Heat question  (Read 5020 times)

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sally125

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Heat question
« on: February 24, 2006, 09:56:43 PM »
I thought I was getting good at these questions but I am quite stumped by this one.  Using Hess' law I found that the deltaH of Mg(s) + 2 H2O(l) -> Mg(OH)2(s) + H2(g) is -638.71kJ but I don't know where to go from there.  Any guidance would be greatly appreciated.

The U.S. military uses a “flameless heater” to warm pre-prepared meals for active service
personnel. The heater contains magnesium metal, which reacts with added water to form
magnesium hydroxide in a very exothermic, oxidation-reduction reaction:
Mg(s) + 2 H2O(l) -> Mg(OH)2(s) + H2(g)
The reaction generates enough heat to cook a meal enclosed in a plastic and aluminum foil pouch.
Given the following data:
Hof(H2O,l) = –285.83 kJ mol–1   (Hof being the formation)
Hof(Mg(OH)2,s) = –924.54 kJ mol–1
specific heat of water = 4.184 J g–1 °C–1 density of water = 1.00 g mL–1
how much magnesium metal is needed to supply the heat required to warm 25.0 mL of water from
25°C to 85°C?


Offline Donaldson Tan

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Re:Heat question
« Reply #1 on: February 24, 2006, 10:38:52 PM »
how much heat does 1 mole of Magnesium produce?

how much heat is needed to raise the temperature of 25ml of water by 40oC?

how much magnesium is need to produce the the amount of heat needed to raise the temperature of 25ml of water by 40oC?
"Say you're in a [chemical] plant and there's a snake on the floor. What are you going to do? Call a consultant? Get a meeting together to talk about which color is the snake? Employees should do one thing: walk over there and you step on the friggin� snake." - Jean-Pierre Garnier, CEO of Glaxosmithkline, June 2006

sally125

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Re:Heat question
« Reply #2 on: February 24, 2006, 11:29:35 PM »
Your questions were very helpful and I had done Hess' law wrong.  Thank you.

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