June 23, 2024, 03:47:38 PM
Forum Rules: Read This Before Posting


Topic: Rate Equation for Reversible Reaction  (Read 2068 times)

0 Members and 1 Guest are viewing this topic.

Offline Big-Daddy

  • Sr. Member
  • *****
  • Posts: 1177
  • Mole Snacks: +28/-94
Rate Equation for Reversible Reaction
« on: January 09, 2013, 02:51:43 PM »
The question is:

There is a reversible reaction of form aA + bB  ::equil::  cC + dD (a, b, c and d are stoichiometric coefficients). The rate of the forward reaction is k1*[A]nA*[ B]nB (nA and nB are orders of the reaction). The rate of the backward reaction is k2*[C]nC*[D]nD.

Keq=([C]c*[D]d)/([A]a*[ B]b)

If the "rate of reaction" is defined as the rate of loss of A, then what is the differential rate equation?

I have worked out an expression for Keq in terms of k1, k2 and the various concentrations, but I'm not sure how this helps me reach the differential rate equation for loss of A. That expression is:

k1/k2=Keq*(([C]nC-c*[D]nD-d)/([A]nA-a*[ B]nB-b))

if you need it. Thanks for the help.

Edit: This website will provide valuable background if you have not seen it yet (look at the section on "Equilibrium reactions or opposed reactions": http://en.wikipedia.org/wiki/Rate_equation).

Sponsored Links