December 23, 2024, 07:48:40 AM
Forum Rules: Read This Before Posting


Topic: Partially methylated disilane  (Read 2141 times)

0 Members and 1 Guest are viewing this topic.

Offline Rutherford

  • Sr. Member
  • *****
  • Posts: 1868
  • Mole Snacks: +60/-29
  • Gender: Male
Partially methylated disilane
« on: March 21, 2013, 01:37:42 PM »
From 20 mg of partially methylated disilane, Si2H6-x(CH3)x, 27.8 cm3 of hydrogen are evolved during alkaline hydrolysis at 294 K and 97400 Pa. Calculate the degree of substitution x of the methylated disilane. Only Si-H and Si-Si bonds break.

I know to solve this, except one thing, the reaction. For example, the cleavage of the Si-H bond, I thought is:
Si-H+OH- :rarrow: Si-OH+1/2H2
while it actually is:
Si-H+H2O :rarrow: Si-OH+H2
How could I known that it is the second reaction and not the first, when they said that it is an alkaline hydrolysis, so I expected OH- ions to participate? Where is the logic behind this?

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27887
  • Mole Snacks: +1815/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Partially methylated disilane
« Reply #1 on: March 21, 2013, 03:10:52 PM »
Si-H+OH- :rarrow: Si-OH+1/2H2

It can't be right for a very simple reason.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline Rutherford

  • Sr. Member
  • *****
  • Posts: 1868
  • Mole Snacks: +60/-29
  • Gender: Male
Re: Partially methylated disilane
« Reply #2 on: March 21, 2013, 03:41:49 PM »
 ::) The charges can't be balanced. I just couldn't notice it. Thanks.

Sponsored Links