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Topic: Pure Liquid HCl !  (Read 2934 times)

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Offline seniour_baloch

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Pure Liquid HCl !
« on: April 15, 2013, 07:38:47 AM »
I read water is essential for any acid. When HCl is dissolved in water, it produces H+ ions which cause the litmus paper to change it colour! But if HCl gas is liquidified and then tested with liquid, what would be the results? As wel as this pure liquid HCl is corrosive or not?

Offline Arkcon

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Re: Pure Liquid HCl !
« Reply #1 on: April 15, 2013, 07:59:06 AM »
Look at the periodic table.  What sort of compound is liquid hydrogen chloride?  You may be able to come up with a conclusion that would be helpful to you on an exam.  Let's see it.
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Offline delta609

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Re: Pure Liquid HCl !
« Reply #2 on: April 15, 2013, 09:49:11 PM »
The thing about acids being corrosive isn't that they "eat" through materials. It's the fact that they react through materials.  If the HCl isn't dissociated in water it's not as prone to react, hence less corrosive. 

Offline Mitch

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Re: Pure Liquid HCl !
« Reply #3 on: April 16, 2013, 12:12:54 AM »
I think HCl would still be highly reactive even in the gas phase, am I just really wrong in thinking this?
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Offline Arkcon

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Re: Pure Liquid HCl !
« Reply #4 on: April 16, 2013, 08:19:09 AM »
I would bet it would corrode ferrous metals rapidly, gaseous or liquid.  However, addressing the original posting: liquified anhydrous hydrogen chloride, would it dissociate into H+ and Cl-?  Compare and contrast: ionization of glacial acetic acid (note: I didn't ask if it can hurt your hand) or perhaps, the ionization of molten NaCl -- in what situations does ionization occur?  And why?
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Offline 9-92-6-19

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Re: Pure Liquid HCl !
« Reply #5 on: April 16, 2013, 09:17:39 PM »
HCl would not be an acid if it were cooled down into the liquid phase; it would be more appropriately hydrogen chloride, not hydrochloric acid. That being said, if there is any water in the air then it will protonate H2O and act like an acid.
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