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Topic: Is my reasoning correct? [Solubility]  (Read 1763 times)

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Offline MangoPlant

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Is my reasoning correct? [Solubility]
« on: May 25, 2013, 07:47:33 PM »
Hello. I was just wondering if someone could confirm whether my reasoning is correct or point to some flaws?

Given that PbCO3  is less soluble than PbI2, and that precipitates are formed when either CO32- or I- ions are added to a aqueous solution of Pb2+, what would happen if CO32- ions were added to a mixture of PbI2 crystals in a large beaker of water?

My reasoning: Since PbCO3 is less soluble than PbI2 the CO32- ions would react with whatever few Pb2+ are formed from the very little dissociation of PbI2 and precipitate out as PbCO3, which will shift the equilibrium of PbI2 to the right (into it's dissociated ions), and if enough CO32- ions are added eventually the equilibrium will keep shifting and all of the PbI2 will disappear.

Offline Corribus

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Re: Is my reasoning correct? [Solubility]
« Reply #1 on: May 25, 2013, 08:47:05 PM »
Your general reasoning seems sound. 
What men are poets who can speak of Jupiter if he were like a man, but if he is an immense spinning sphere of methane and ammonia must be silent?  - Richard P. Feynman

Offline 408

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Re: Is my reasoning correct? [Solubility]
« Reply #2 on: May 25, 2013, 11:12:57 PM »
This is exactly what will happen.

Offline MangoPlant

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Re: Is my reasoning correct? [Solubility]
« Reply #3 on: May 26, 2013, 05:29:26 PM »
Thanks Corribus and 408.  :)

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