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Topic: Calculating Equilibrium Constant - my solution is right or wrong?  (Read 3207 times)

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Offline be7cailay

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Hello guys, I don't know my solution is right or wrong. Please correct me! thank you very much :)

Problem:
Ordinary white phosphorus, P4, forms a vapor which dissociates into diatomic molecules at high temperatures:   P4(g)→ 2 P2(g)

A sample of white phosphorus, when heated to 1000°C, formed a vapor having a total pressure of 0.20 atm and a density of 0.152 g L–1. Use this information to evaluate the equilibrium constant Kp for this reaction.




Offline be7cailay

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Re: Calculating Equilibrium Constant - my solution is right or wrong?
« Reply #1 on: July 13, 2013, 12:36:41 AM »
Oh! I just realize that the density part is wrong  :'(

Offline magician4

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Re: Calculating Equilibrium Constant - my solution is right or wrong?
« Reply #2 on: July 13, 2013, 06:12:57 AM »
the average density [itex]\rho_{av}[/itex] of a gas mixture of A , B is to be calculated as follows:

[tex] \rho_{av} \ = \ \chi (A) \cdot \rho_{pure}(A) \ + \ \chi (B) \cdot \rho_{pure}(B) [/tex]


besides that, your thoughts as represented by the paper are a little hard to follow, but seem ok to me

nevertheless, you should keep in mind that the final dimension of your Kp should be [atm] in this case: the result is not a scalar (as shown)

regards

Ingo
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Offline be7cailay

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Re: Calculating Equilibrium Constant - my solution is right or wrong?
« Reply #3 on: July 15, 2013, 06:50:39 PM »
Thank you very much for the density formula, Ingo!! :)

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