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Topic: name of this alkane?  (Read 8416 times)

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Offline iScience

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name of this alkane?
« on: August 30, 2013, 08:54:04 PM »
http://i.imgur.com/pLsKEy1.png

I thought this was  4-tert-butyl-3-methylheptane but a site is telling me that this is wrong. please explain to me why this is not that
« Last Edit: August 30, 2013, 08:56:54 PM by Arkcon »

Offline iScience

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Naming more alkanes..
« Reply #1 on: August 30, 2013, 09:52:01 PM »
http://i.imgur.com/fZIMI1v.jpg

So, why is this "4-sec-butyl-6-isopropyl-5-neopentylnonane" instead of "6-sec-butyl-4-isopropyl-5-neopentylnonane"?

i thought one of the rules was to assign the lower number to the one that is earlier in the alphabet, and since "sec" and "tert" are not alphabetized in nomenclature, we don't worry about them.

(by the way, if sec and tert aren't alphabetized in nomenclature, do they always go in the front?)

Offline discodermolide

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Re: name of this alkane?
« Reply #2 on: August 30, 2013, 11:29:11 PM »
That looks OK to me.
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Offline discodermolide

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Re: Naming more alkanes..
« Reply #3 on: August 30, 2013, 11:33:22 PM »
ChemDraw says it is
6-isopropyl-3-methyl-5-neopentyl-4-propylnonane
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Offline orgopete

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Re: name of this alkane?
« Reply #4 on: August 31, 2013, 01:07:39 AM »
They might be looking for a nested name, 4-(1,1-dimethylethyl), or something like that.
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Offline Altered State

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Re: Naming more alkanes..
« Reply #5 on: August 31, 2013, 06:20:30 AM »
http://i.imgur.com/fZIMI1v.jpg

So, why is this "4-sec-butyl-6-isopropyl-5-neopentylnonane" instead of "6-sec-butyl-4-isopropyl-5-neopentylnonane"?

i thought one of the rules was to assign the lower number to the one that is earlier in the alphabet, and since "sec" and "tert" are not alphabetized in nomenclature, we don't worry about them.

(by the way, if sec and tert aren't alphabetized in nomenclature, do they always go in the front?)

I think you are saying it yourself, if we don't count on "sec", butyl has preference over "iso" (B > I :) ) at its got to be asigned the lower number.
But it may be as disco says, its some way simpler

Offline Arkcon

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Re: name of this alkane?
« Reply #6 on: August 31, 2013, 06:23:38 AM »
I hope you mind, Altered State: iScience:, that I merged your two posts with the same general topic, "Naming alkanes"  You'll learn better if you have all the questions and answers in one thread, and there will be less clutter in the Forum list.
« Last Edit: August 31, 2013, 11:41:50 AM by Arkcon »
Hey, I'm not judging.  I just like to shoot straight.  I'm a man of science.

Offline Altered State

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Re: name of this alkane?
« Reply #7 on: August 31, 2013, 07:30:50 AM »
I hope you mind, Altered State:, that I merged your two posts with the same general topic, "Naming alkanes"  You'll learn better if you have all the questions and answers in one thread, and there will be less clutter in the Forum list.

I guess you mean iScience, not me :-D

Offline Arkcon

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Re: name of this alkane?
« Reply #8 on: August 31, 2013, 11:40:45 AM »
I hope you mind, Altered State:, that I merged your two posts with the same general topic, "Naming alkanes"  You'll learn better if you have all the questions and answers in one thread, and there will be less clutter in the Forum list.

I guess you mean iScience, not me :-D

Gah.  Sorry.  I wasn't paying enough attention.
Hey, I'm not judging.  I just like to shoot straight.  I'm a man of science.

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