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Topic: Electrolytic cell  (Read 1908 times)

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Offline lalex0710

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Electrolytic cell
« on: October 07, 2013, 03:07:38 PM »
Here's a question that took me a long time and I still couldn't fully figure it out.

An electrolytic cell is set up with an electrolyte H2Se(aq). The  nickel electrodes are weighed before and after the experiment. A voltage supply is set for 0.70 V. The cell is connected. List the primary and secondary equations.

Offline Borek

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Re: Electrolytic cell
« Reply #1 on: October 07, 2013, 04:42:43 PM »
You have to show your attempts at solving the question to receive help. This is a forum policy.

What can happen with Ni?

What is H2Se? Hint: think about its lighter cousin without an 'e'.
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Offline lalex0710

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Re: Electrolytic cell
« Reply #2 on: October 07, 2013, 05:06:42 PM »
I know that Nickel has to be the anode since it is stated to be the electrode, and must be the one undergoing oxidation. 
Ni ---> Ni2+ + 2e- But I couldn't quite figure out which is the cathode of the reaction. I'm also assuming there is a primary and secondary equation since there are three species present, but I don't know which is the primary and which is secondary. So, h2se can also be a cathode right? Then is h2o or is h2se a cathode, or can there be two reactions at the cathode and also the other way around. much help would be appreciated. thanks

Offline Borek

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Re: Electrolytic cell
« Reply #3 on: October 07, 2013, 05:14:36 PM »
You have also water which can react on electrodes.

Think what will happen with Ni2+ in the solution...
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