September 28, 2024, 03:20:28 PM
Forum Rules: Read This Before Posting


Topic: Thermochemistry Question  (Read 2316 times)

0 Members and 1 Guest are viewing this topic.

Offline kauzs-17

  • Regular Member
  • ***
  • Posts: 23
  • Mole Snacks: +0/-0
Thermochemistry Question
« on: November 17, 2013, 11:38:29 PM »
Hello, I'm stuck at a certain part of my question.
This is the original question: If all the energy obtained from burning 1.00 pound of propane is used to heat water, how many kg of water can be heated from 20.0°C to 45.0°C?

So, I converted lbs > g > moles of propane and multiplied it by the given ΔHcomb, which is -2219.9. However, the way my professor showed it done, the + amount of moles times the -ΔHcomb resulted in a positive q(heat). Why wouldn't the answer be negative?
I'm guessing it might be because when you burn propane you're getting energy as a product, but I didn't think you could just change the sign like that.

Offline Corribus

  • Chemist
  • Sr. Member
  • *
  • Posts: 3530
  • Mole Snacks: +541/-23
  • Gender: Male
  • A lover of spectroscopy and chocolate.
Re: Thermochemistry Question
« Reply #1 on: November 17, 2013, 11:42:07 PM »
The sign of the enthalpy just tells you whether heat is consumed or released by the reaction.  (The negative sign tells you it's being released, which shouldn't be unexpected for a combustion.)  Now find out how much water that amount of heat (absolute value) can change the water's temperature over the range specified.. 
What men are poets who can speak of Jupiter if he were like a man, but if he is an immense spinning sphere of methane and ammonia must be silent?  - Richard P. Feynman

Offline kauzs-17

  • Regular Member
  • ***
  • Posts: 23
  • Mole Snacks: +0/-0
Re: Thermochemistry Question
« Reply #2 on: November 17, 2013, 11:48:20 PM »
So basically qwater = -qpropane, correct? What leaves the propane (q<0) goes to the water (q>0)?

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27797
  • Mole Snacks: +1808/-411
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Thermochemistry Question
« Reply #3 on: November 18, 2013, 02:52:05 AM »
What leaves the propane (q<0) goes to the water (q>0)?

Exactly.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Sponsored Links