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Topic: HI reaction  (Read 2319 times)

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Offline Bassel

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HI reaction
« on: December 13, 2013, 08:41:00 AM »
i know that an HI can break a Πbond of a double bond in an electrophilic addition reaction of alekens ,but what is the name of this reaction in which the I- broke a {σ bond} between a carbon and an O in this ring ?
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Online Babcock_Hall

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Re: HI reaction
« Reply #1 on: December 13, 2013, 11:32:43 AM »
To which ring are you referring?  A diagram may help.
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Offline Bassel

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Re: HI reaction
« Reply #2 on: December 13, 2013, 12:43:05 PM »
sorry i forgot to upload the diagram
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Online Babcock_Hall

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Re: HI reaction
« Reply #3 on: December 13, 2013, 04:04:40 PM »
I am not aware of a name for this reaction (like a Finkelstein reaction, for example).  It is just the conversion of an ether into an iodoalkane, as far as I know.
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Offline antimatter101

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Re: HI reaction
« Reply #4 on: December 13, 2013, 04:43:07 PM »
Its the cleavage of an ether by strong acids. Only HBr and HI can do this trick.
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Online Babcock_Hall

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Re: HI reaction
« Reply #5 on: December 13, 2013, 04:57:57 PM »
Iodotrimethylsilane can also do an analogous reaction.
« Last Edit: December 13, 2013, 05:39:25 PM by Babcock_Hall »
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Offline zsinger

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Re: HI reaction
« Reply #6 on: December 13, 2013, 04:59:05 PM »
I think Sn2?
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