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Topic: mno4 and h2s04  (Read 3000 times)

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Offline sumitsaurav

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mno4 and h2s04
« on: December 13, 2013, 12:56:08 PM »
20 ml of M-kmno4 soln is diluted to 150 ml.in that soln 50 ml of 10  M- H2so4 is added 25 ml of this mxture is titrate with 20 ml Fec204 soln.the molarity of Fec204 soln is?
 1] 0.0416
2] 0.208
3] 0.625
4] 0.125

Offline Hunter2

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Re: mno4 and h2s04
« Reply #1 on: December 13, 2013, 01:13:59 PM »
Its really hard to read. Use for kmno4 KMnO4 and asked again. And show your attempt where you have difficulties to calculate or understand.

Offline Radu

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Re: mno4 and h2s04
« Reply #2 on: January 05, 2014, 04:38:00 PM »
  You need to take into account that Fe2+ is oxydized to Fe3+ and C2O42- is oxydized to CO2. Mn7+ is reduced to Mn2+. If you still don't get your answer, take into consideration the reduction of manganese to Mn3O4, a very stable manganese compund often precipitated after acidic REDOX processes.

Offline Borek

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Re: mno4 and h2s04
« Reply #3 on: January 05, 2014, 05:32:58 PM »
take into consideration the reduction of manganese to Mn3O4, a very stable manganese compund often precipitated after acidic REDOX processes.

MnO2 is what precipitates typically when the pH is not low enough.
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