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Topic: DMSO anion as base  (Read 1708 times)

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Offline AlphaScent

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DMSO anion as base
« on: June 16, 2014, 10:51:23 AM »
does the sodium or lithium carbanion of DMSO have to be made in situ or can you buy it?  Cannot seem to find in from aldrich.
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Offline discodermolide

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Re: DMSO anion as base
« Reply #1 on: June 16, 2014, 12:16:31 PM »
You have to make it. Be careful with it.
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Offline AlphaScent

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Re: DMSO anion as base
« Reply #2 on: June 16, 2014, 02:22:50 PM »
I was just talking to my professor.  He said it is kind of a pain.  Getting rid of the DMSO and all.  I was reading an organic syntheses paper on making a terminal double bond via a Wittig.  They mention that using the DMSO anion and DMSO gives higher yields. 

Was just wondering if its worth it.  Have to do some reading about it.

Thanks Disco.
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