Right, by the sounds of it, the steam has pushed out all the other gases in the bottle and when corked, contains just steam. If you cool the steam, you decrease the pressure by condensing the steam into water, lowering the pressure and boiling point. If you put a little water in a soda can, boil it over the stove and turn it upside down in a bowl of cold water, the pressure will decrease in the can that only has steam in it and the atmospheric pressure will crush the can.