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Topic: Copper(I) oxide in aqueous solution  (Read 2101 times)

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Offline cyclopentadienyl

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Copper(I) oxide in aqueous solution
« on: December 03, 2014, 07:08:29 AM »
Hello

I hope you are able to help me. This is my task: Copper(I) oxide is suspended in a solution of Cu(II) ions (c(Cu(II))=0.01 mole/l, temperature 20 °C [68 °F], Ksp(CuOH)=1.0*10^-15).
Calculate the pH value form copper(I) oxide is stable in aqueous solution. Does the temperature have an influence to the pH?
It would be enough if you could provide me with the correct equation(s).

I thank you very much in advance.

cyclopentadienyl
« Last Edit: December 03, 2014, 08:38:17 AM by cyclopentadienyl »

Offline billnotgatez

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Re: Copper(I) oxide in aqueous solution
« Reply #1 on: December 03, 2014, 07:22:02 AM »
We are a teaching forum here and forum rules require you show some work.
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Offline cyclopentadienyl

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Re: Copper(I) oxide in aqueous solution
« Reply #2 on: December 03, 2014, 07:50:52 AM »
Hello billnotgatez

Sorry for that.
I know that copper(I) oxide which is dissolved in water forms Cu(I) ions as well as extremely reactive O2- ions. These ions react with water to OH- ions which change the pH value. So, the solubility of salts depends on the pH.
Cu2O + H2O  :rarrow: Cu+ + 2OH-

Furthermore: Kps=c(Cu(II))*c(Cu(I))²
                   c(CU(I))=sq root[Kps/c(Cu(II))].

                   c(Cu(I))=3.16*10^-7 mole/l
« Last Edit: December 03, 2014, 08:37:47 AM by cyclopentadienyl »

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