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Topic: Ethylene carbonate as a source of ethylene oxide  (Read 2824 times)

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Offline blueberry58

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Ethylene carbonate as a source of ethylene oxide
« on: February 14, 2015, 10:00:13 PM »
Looking for ethylene trithiocarbonate preparation  I found a nice title on Google "One-pot synthesis of ethylene trithiocarbonate from ethylene carbonate". This prep uses ethylene carbonate as source of ethylene oxide. The article requires some payment in  ScienceDirect.

Someone knows the details of this reaction? Its possible use EC as source of EO in others reactions?

Thank you.

Offline billnotgatez

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Re: Ethylene carbonate as a source of ethylene oxide
« Reply #1 on: February 15, 2015, 11:15:16 AM »
I went to WIKI and could not find the compound Ethylene trithiocarbonate.
So I did a GOOGLE and found the article mentioned previously for just under $40.
But, Ethylene Trithiocarbonate seems to be esoteric enough that it is not on WIKI although it seems to be readily available at suppliers.

Ethylene trithiocarbonate   
Ethylene trithiocarbonate, 822-38-8, C3H4S3, FW 136.26 is a yellow crystalline powder.
Ethylene trithiocarbonate is 97+% pure and has a melting point 34 – 35 °C.
Ethylene trithiocarbonate is being used in cancer research.
General Information on Ethylene trithiocarbonate
CAS No. : 822-38-8
Synonym : 1,3-Dithiolane-2-thione
Properties of Ethylene trithiocarbonate :
Appearance/Form: Yellow crystalline powder
Formula: C3H4S3
Molecular Weight: 136.26
MP: 34 – 35 °C (93 – 96 °F)
BP: 307 °C (585 °F)
Flash Point: 163 °C (325 °F) in a closed cup
Storage : Keep tightly closed in a dry, well-ventilated place
Uses of Ethylene trithiocarbonate
In cancer research
Transport Information for Ethylene trithiocarbonate
Proper Shipping Name: Aviation regulated solid, n.o.s (1,3-Dithiolane-2-thione
UN3335
Class: 9

http://www.citychemical.com/ethylene-trithiocarbonate.html

Offline billnotgatez

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Re: Ethylene carbonate as a source of ethylene oxide
« Reply #2 on: February 15, 2015, 11:23:03 AM »
@blueberry58

Are you interested in
Ethylene trithiocarbonate 
or
ethylene carbonate
  https://en.wikipedia.org/wiki/Ethylene_carbonate
or
ethylene oxide
  https://en.wikipedia.org/wiki/Ethylene_oxide


Offline blueberry58

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Re: Ethylene carbonate as a source of ethylene oxide
« Reply #3 on: February 15, 2015, 10:43:04 PM »
Thank you for your help billnotgatez. I am reading this information.

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