The question wants me to calculate the "second electron affinity" of oxygen from the following data:
"First electron affinity" of oxygen: -141 kJ/mol
Lattice energy of K2O: 2238 kJ/mol
The following it says to find in tables and appendix, so here's the rest of what I believe I need:
?Hf[K2O(s)]: -363.2 kJ/mol
?Hf[K(g)]: 89.99 kJ/mol
?Hf[O(g)]: 247.5 kJ/mol
I11(K): 419 kJ/mol
This is the formula I've been trying to use,
?Hf[K2O(s)]=?Hf[K(g)] + ?Hf[O(g)] + 2I11(K) + E1(O) + E2(O) - ?HLattice
Thus plugging in the numbers,
-363.2 = 89.99 + 247.5 + 2(419) + (-141) + E2 - 2238
This comes out to E2 = +840 kJ/mol, but the back of the book says +750kJ. Where am I going wrong?