Sometimes these mechanisms are best worked backwards in order to understand what is otherwise implausible. If you were referring to a Markovnikov addition, the electrons of an alkene can seem like an unlikely donor. If you must rationalize how the product formed, then an addition of a proton to a carbon can be seen as a general event with many examples. If thought of in that way, then an addition seems more reasonable. Even so, the addition is probably a kinetic event with low concentrations of the intermediate, consistent with your question, but once formed, even in small concentrations, leads to product.