For the moment, just stick to moles. Just by inspection of the stoichiometry, you can determine the relationship between the products and reactants.
By the first equation, 2 moles of ZnO will produce 2 moles of Zn.
By the second equation, 3 moles of Zn will product 2 moles of Au.
Therefore, 1 mole of ZnO will produce how many moles of Au? The answer is
1 mole ZnO X (2 moles of Zn / 2 moles of ZnO) X (2 moles of Au / 3 moles of Zn), or 2/3.
As I was trying to tell you in your other thread, if having two equations confuses you, you can combine them into one so that it is more straightforward to see the molar relationship. This does require that you balance your new equation.
I.e., you can add the left hand side of each equation and the right hand side of each equation thusly:
2ZnO + C + 2Au
3+ + 3Zn
2Zn + CO
2 + 3Zn
2+ + 2Au
You'll notice that the amount of Zn on the left hand side does not equal the amount of Zn on the right hand side, so this new equation isn't balanced. You can balance it easy enough by multiplying everything on the left by 2 and everything on the right by 3 to get:
4Zn + 2C + 4Au
3+ + 6Zn
6Zn + 3CO
2 + 9Zn
2+ + 6Au
Now it should be clear that 4 moles of Zn yields 6 moles of Au, or 1 mole of Zn yields 2/3 moles of Au. Effectively you've done the same thing via both procedures, but sometimes it is easier to see it when it's in one reaction equation.
Once you have the mole ratios figured out, you can do your mass conversion and solve the problem.