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Topic: Coordination complexes help  (Read 2225 times)

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Offline mrdoovde1

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Coordination complexes help
« on: May 12, 2015, 10:50:23 PM »
Ok, so I am posed the following statement and am asked to give the oxidation states:



A = [Fe(H2O)6]2- - Oxidation state of Fe is in +2

B = [Fe(CN)6]-6 - Oxidation state is 0

C = Ignore as complex isn't important in this case. Oxidation state is +3

D = Fe(SCN)- - Oxidation state is +1

Are the complexes and oxixdation states

Also, what do the colours in the statement tell you about the complex?

Thanks

Offline Borek

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Re: Coordination complexes help
« Reply #1 on: May 13, 2015, 02:52:27 AM »
I am afraid most of your answers are wrong, I guess you are misunderstanding some of the basic principles.

First of all - changing the ligand doesn't change the oxidation state, for the change of the oxidation state you need a redox reaction, there is only one such reaction here.

Please elaborate why you think the formula of hexaaqua ion is Fe(H2O)6]2-, and why you think oxidation state of Fe in this ion is +2.
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Offline mrdoovde1

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Re: Coordination complexes help
« Reply #2 on: May 13, 2015, 07:53:31 AM »
I am afraid most of your answers are wrong, I guess you are misunderstanding some of the basic principles.

First of all - changing the ligand doesn't change the oxidation state, for the change of the oxidation state you need a redox reaction, there is only one such reaction here.

Please elaborate why you think the formula of hexaaqua ion is Fe(H2O)6]2-, and why you think oxidation state of Fe in this ion is +2.

How do you identify a redox reaction?

Also since the Fe atom was initially in an oxidation state +2, when the 6 H2O ligands are attached to it, it will remain in a +2 oxidation state. This mean that the overall charge must be -2 since H2O ligands are neutral


Edit: Just realised I made a mistake. For the reason mentioned above, it should be Fe(H2O)6]2+ not 2-
« Last Edit: May 13, 2015, 08:12:06 AM by mrdoovde1 »

Offline Borek

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Re: Coordination complexes help
« Reply #3 on: May 13, 2015, 02:22:11 PM »
How do you identify a redox reaction?

Not a thing easy to answer without a specific context. However, the way the question is worded it looks like A and B are compounds of Fe(II), while C and D are compounds of Fe(III).
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