I'd like to welcome you,
bitsi:, the the Chemical Forums but I'd like to ask you to read the
Forum Rules{click}. We like to help you learn to help yourself. Can you begin to show us your attempt?
OK, start with a balanced chemical equation. Write it out carefully in chemical notation. Can you can use that to determine how much perchlorate there was in your original sample based on the mass of oxygen?
I'm going to start on the math right now, you mass of oxygen seems ... high to me.