December 23, 2024, 07:09:34 PM
Forum Rules: Read This Before Posting


Topic: Orbital mixing: propene vs acrolein  (Read 1239 times)

0 Members and 1 Guest are viewing this topic.

Offline orgo814

  • Full Member
  • ****
  • Posts: 412
  • Mole Snacks: +11/-6
Orbital mixing: propene vs acrolein
« on: February 04, 2016, 10:21:59 PM »
When comparing propene and acrolein (pi CH3 mixing with pi C-C or pi C-O), we know that the mixing is stronger in acrolein because the C-O is lower in energy, thereby lessening the energy gap between pi CH3. Because of this stronger mixing, does this result in a higher magnitude energy drop for the BO and higher magnitude energy raise for the antibonding orbital. I'm comparing the two MO diagrams in my textbook but it's obviously hard to visually compare them and wasn't made obvious.

Sponsored Links