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Topic: Kinneticaly equvialent therms  (Read 2762 times)

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Offline kapital

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Kinneticaly equvialent therms
« on: February 18, 2016, 08:47:28 AM »
In rate law I find therm Kinetically equivalent terms. Can somebody please explain me, what does this mean?
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Offline mjc123

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Re: Kinneticaly equvialent therms
« Reply #1 on: February 18, 2016, 08:54:34 AM »
I'm not sure, without a context. Can you quote the sentence or paragraph where this phrase is used?
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Offline kapital

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Re: Kinneticaly equvialent therms
« Reply #2 on: February 22, 2016, 04:45:39 AM »
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Offline mjc123

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Re: Kinneticaly equvialent therms
« Reply #3 on: February 22, 2016, 04:58:04 AM »
It is defined in the immediately following words: they are "indistinguishable from each other in a rate expression". That is, they have the same dependence on concentration of reagents (here H+) and analysis would yield a single rate constant (which here, for B and D for example, would be a combination of k2, k4 and Ka).
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