September 28, 2024, 02:12:57 PM
Forum Rules: Read This Before Posting


Topic: Triol oxidation with KMnO4  (Read 2219 times)

0 Members and 1 Guest are viewing this topic.

Offline Andy_Ruan

  • New Member
  • **
  • Posts: 5
  • Mole Snacks: +0/-0
Triol oxidation with KMnO4
« on: April 03, 2016, 03:22:41 PM »
Does anyone know the products for 4,5-diethyl-1,3,5-nonanetriol + KMnO4 --->

For these reactions, do we treat the OH groups seperately, so the
C#1 OH becomes aldehyde group
C#3 OH becomes ketone
(I am not sure if tertiary OH on C#5 can be oxidized)

Thanks in advance!

Offline orgopete

  • Chemist
  • Sr. Member
  • *
  • Posts: 2636
  • Mole Snacks: +213/-71
    • Curved Arrow Press
Re: Triol oxidation with KMnO4
« Reply #1 on: April 04, 2016, 11:12:28 AM »
Hint: if water were to add to a carbonyl group, are the resulting OH groups oxidizable?
Author of a multi-tiered example based workbook for learning organic chemistry mechanisms.

Sponsored Links