[Morphic flip]

I can`t write down other complexes of Co<sub>(py)2</sub>(SCN)<sub>2</sub> like I have just written here.
It`s polymer isomers I need of this molecule, but only with one Co atom.
I can`t see how to express the isomers.

[AWK]

Your complex is very like tetrahedral, and rather have no isomers. The only possibility is coordination by N or S atoms

[Morphic flip]

I was thinking thiocyanate ligand can bond by either the N or S, how would I write/express that?
Or is it the same as I`ve put?
Is there no other way`s of expressing the example I have given?

[AWK]

http://www.chemicalforums.com/index.php?topic=8032.msg36210#msg36210

[Morphic flip]

Thank`s.

[Will]

I was thinking thiocyanate ligand can bond by either the N or S, how would I write/express that?
Or is it the same as I`ve put?
Is there no other way`s of expressing the example I have given?

In a thiocyanate ligand- it always bonds to the S (-SCN), only in isothiocyanate ligands does it bond to the N (-N=C=S).

[AWK]

Strictly speaking - will17 is absolutely right - I meant that using thiocyanate we can obtain a mixed complex containing both: thiocyanate ligands and isothiocyanate ligands (thiocyanate but bonded to N atom)

[Morphic flip]

Hmm, interesting, thank`s for the info.

[AWK]

I searched CSD database. Such a complex axist, ist polymeric with octahedral environment of Co with two CoS bond and complexe with two CO-N donating bonds.

[AWK]

I searched CSD database. Such a complex is known and polymeric. Coballt forms two CoS bond, two Co-N(py) datyve bonds, ans two Co-NCS dative bonds with coordination number 6 (octahedral complex)

[Morphic flip]

What free download etc did you use to check?
Regards.

[AWK]

Reference: M.A.Porai-Koshits, G.N.Tishchenko (1960)
Kristallografiya(Russ.)(Crystallogr.Rep.) ,4,239

catena-Cobalt(ii) thiocyanate-pyridine

[Morphic flip]

Thank`s.